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Detection of polycyclic aromatic hydrocarbon (PAH) compounds in artificial sea-water using surface-enhanced Raman scattering (SERS) ArchiMer
Peron, Olivier; Rinnert, Emmanuel; Lehaitre, Michel; Crassous, Philippe; Compere, Chantal.
This paper reports an accurate synthesis of surface-enhanced Raman scattering (SERS) active substrates, based on gold colloidal monolayer, suitable for in situ environmental analysis. Quartz substrates were functionalized by silanization with (3-mercaptopropyl)trimethoxysilane (MPMS) or (3-aminopropyl)trimethoxysilane (APTMS) and they subsequently reacted with colloidal suspension of gold metal nanoparticles: respectively, the functional groups SH and NH2 bound gold nanoparticles. Gold nanoparticles were prepared by the chemical reduction of HAuCl4 using sodium tricitrate and immobilized onto silanized quartz substrates. Active substrate surface morphology was characterized with scanning electron microscopy (SEM) measurements and gold nanoparticles...
Tipo: Text Palavras-chave: Sensor; Sea water; PAH detection; SERS; Silanization; Gold nanoparticles.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-6616.pdf
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First Steps of in Situ Surface-Enhanced Raman Scattering During Shipboard Experiments ArchiMer
Peron, Olivier; Rinnert, Emmanuel; Colas, Florent; Lehaitre, Michel; Compere, Chantal.
It is shown that the surface-enhanced Raman scattering (SERS) technique can be applied to detect organic molecules during in situ experiments. To this purpose, we used trans-1,2-bis(4-pyridyl)ethylene (BPE) as a target molecule. Adsorbed on the SERS chemosensor surface and excited under laser, the vibration modes of the molecules can be identified. SERS chemosensors are based on quartz substrates functionalized by silanization and partially coated with gold nanoparticles. SERS measurements during shipboard experiments were made with a home-made in situ Raman spectrometer connected to a marinized micro-fluidic system. The device was designed to host chemosensors in order to ensure measurements with a flow cell. A theoretical limit of detection was estimated...
Tipo: Text Palavras-chave: Surface-enhanced Raman scattering; SERS; Chemosensors; Flow cells; Shipboard experiments; In situ measurements; Freundlich isotherm.
Ano: 2010 URL: http://archimer.ifremer.fr/doc/00016/12691/9718.pdf
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New trends in plasmonic (bio)sensing Anais da ABC (AABC)
MEJÍA-SALAZAR,JORGE R.; CAMACHO,SABRINA A.; CONSTANTINO,CARLOS J.L.; OLIVEIRA JUNIOR,OSVALDO N..
Abstract The strong enhancement and localization of electromagnetic field in plasmonic systems have found applications in many areas, which include sensing and biosensing. In this paper, an overview will be provided of the use of plasmonic phenomena in sensors and biosensors with emphasis on two main topics. The first is related to possible ways to enhance the performance of sensors and biosensors based on surface plasmon resonance (SPR), where examples are given of functionalized magnetic nanoparticles, magnetoplasmonic effects and use of metamaterials for SPR sensing. The other topic is focused on surface-enhanced Raman scattering (SERS) for sensing, for which uniform, flexible, and reproducible SERS substrates have been produced. With such recent...
Tipo: Info:eu-repo/semantics/article Palavras-chave: Plasmonics; Biosensing; Sensing; SERS; Magnetoplasmonics; TMOKE.
Ano: 2018 URL: http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0001-37652018000200779
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Sensing Polymer/Paracetamol Interaction with an Independent Component Analysis-Based SERS-MIP Nanosensor ArchiMer
Decorbie, N.; Tijunelyte, I.; Gam-derouich, S.; Solard, J.; Lamouri, A.; Decorse, P.; Felidj, N.; Gauchotte-lindsay, C.; Rinnert, Emmanuel; Mangeney, C.; Lidgi-guigui, N..
In this article, we propose a new strategy to build a sensor for easy handling and rapid analysis on-site. Our sensor is based on the combination of surface-enhanced Raman spectroscopy (SERS) and molecularly imprinted polymers (MIPs). SERS provides a strong sensitivity for the detection of trace molecules while MIPs offer a highly selective and specific recognition platform. The research presented here focuses on the detection of the interaction between a robust ultra-thin layer of MIPs and of paracetamol, the targeted molecule. This drug is an environmental emerging pollutant, i.e., a molecule whose presence and significance have not yet been elucidated, which gives rise to health and environmental concerns. The results are a combined analysis of the SERS...
Tipo: Text Palavras-chave: Sensor; SERS; Molecularly imprinted polymers; Emerging pollutant; Paracetamol; Independent component analysis.
Ano: 2020 URL: https://archimer.ifremer.fr/doc/00628/73962/73386.pdf
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Simple and rapid detection of pesticides and chemicals using surface enhanced Raman spectroscopy OAK
角田, 英男; 上元, 好仁; 堀川, 洋.
独自の銀ナノ粒子・基板を試作し,小型ラマン分光装置を用いジチオカーバメート系農薬(Thiram: tetramethylthiuram disulfide)・パルノックスおよびメラミンのラマンおよび表面増強ラマン(Surface Enhanced Raman Spectroscopy:SERS)スペクトルの計測を行った。濃度が4ppm から0.04ppmの範囲では,濃度とピーク強度との間に良い直線関係が示された。同様に小麦粉に混合したメラミンのラマンスペクトルおよびSERS スペクトルを顕微ラマン分光装置により計測した。1ppm濃度程度まで特有のSERS 吸収ピークが観測され,定性的検出が可能であった。この銀ナノ粒子・基板を用いた小型で安価な装置による表面増強ラマン(SERS)スペクトル計測は,農薬や化学物質の分析法として感度が高く実用性が十分あると考えられた。
Palavras-chave: 迅速簡便; ラマン分光; SERS; 農薬; メラミン; Simple and rapid Raman spectroscopy; SERS; Pesticides; Melamine.
Ano: 2009 URL: http://ir.obihiro.ac.jp/dspace/handle/10322/2651
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Towards in situ detection of PAH trace in sea-water using SERS-active sensors ArchiMer
Peron, Olivier; Rinnert, Emmanuel; Lehaitre, Michel; Colas, Florent; Compere, Chantal.
This paper reports the development of a sensor based on surface-enhanced Raman scattering (SERS) for analyses in sea-water. Polycyclic aromatic hydrocarbons (PAHs) are targeted by these sensors and their detection in situ summons up chemical synthesis and optical development. Firstly, a relevant synthesis of SERS active substrates based on gold nanostructures is presented. Different kinds of substrates have been synthesized under variable experimental conditions to modify some parameters such as i) gold shape, size and distribution and such as ii) chemical functionalization: (i) gold nanoparticles were prepared either by chemical reduction of HAuCl4 or by physical deposition. (ii) Substrates were functionalized by hydrophobic films to allow nonpolar...
Tipo: Text Palavras-chave: Functionalization; Silanization; Gold nanostructures; SERS; PAH detection; Sea-water; Sensor; In situ.
Ano: 2009 URL: http://archimer.ifremer.fr/doc/00012/12363/9152.pdf
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